当前位置：首页 > 过刊浏览->2024年第35卷第6期
生物基衍生物2，5-呋喃二甲酸的合成研究进展
Research progress on the synthesis of bio-based derivative 2, 5-furandicarboxylic acid
浏览(344) 下载(4)
- DOI:
- 作者:
- 廖文博1 ，孙 勇1，2 ，姜 伟3 ，赵臣康3 ，祖 钰3 ，郭鸿宇3
Liao Wenbo 1 , Sun Yong 1, 2 , Jiang Wei 3 , Zhao Chenkang 3 , Zu Yu 3 , Guo Hongyu 3
- 作者单位:
- 1. 厦门大学能源学院厦门市生物质清洁高效利用重点实验室，福建 厦门 361102；2. 厦门大学能源学院福建省生物质清洁高值化工程技 术研究中心，福建 厦门 361102；3. 中国石油石油化工研究院大庆化工研究中心，黑龙江 大庆 163714
1. Xiamen Key Laboratory of Clean and Efficient Utilization of biomass, College of Energy, Xiamen University, Xiamen 361102, China; 2. Fujian Biomass Clean & High-value Engineering Technology Research Center, Xiamen 361102, China; 3. PetroChina Petrochemical Research Institute Daqing Petrochemical Research Center, Daqing 163714, China
- 关键词:
- 5-羟甲基糠醛；2，5-呋喃二甲酸；催化氧化；非均相体系
5-hydroxymethylfurfural; 2,5-furandicarboxylic acid; catalytic oxidation, heterogeneous system
- 摘要:
- 摘要：生物质基平台化合物2，5-呋喃二甲酸（2，5-furandicarboxylic acid，FDCA）具有很高的应用前景。目前FDCA已经广泛应用于石油化工，抗肿瘤药物，高性能环保涂料，合成新型聚合物等领域。由于5-羟甲基糠醛（5-hydroxymethyl furfura，HMF）廉价、易得、化学性质稳定等优点已被普遍认为是用来制备FDCA最优秀的原材料。为此，文中全面总结了近年来以HMF为原材料催化氧化制备FDCA的合成工艺的研究进展。其中，重点介绍了非均相体系金属催化剂的研究进展，并对非金属催化剂以及光催化体系和电催化体系的相关研究进行了总结。同时，系统地阐述了不同反应催化剂下HMF制备FDCA的优缺点。最后，讨论了由HMF催化氧化为FDCA目前所面临的各种挑战，并对未来可能的研究方向提出了相关见解。Abstract: Biomass based platform compound 2, 5-Furandicarboxylic acid (FDCA) has a high application prospect, which has beenwidely used in petrochemical industry, anti-tumor drugs, high-performance environmental protection coatings, synthesis of newpolymers and other fields. 5-hydroxymethyl furfura (HMF) has been widely regarded as the best raw material for preparing FDCAdue to its advantages of cheap, easy to obtain and stable chemical properties. This paper reviewed the recent progress in thesynthesis of FDCA by catalytic oxidation of HMF, introduced the research progress of metal catalysts in heterogeneous systems,summarized the related researches on non-metallic catalysts, photocatalytic systems and electrocatalytic systems, discussed system⁃atically the advantages and disadvantages of preparation of FDCA by HMF under different reaction catalysts, and finally discussedthe challenges of catalytic oxidation from HMF to FDCA and proposed the possible research directions in the future.