1-辛烯合成技术进展
Progress in synthesis technology of 1- octene
于杨
作者单位:中国石油集团长城钻探工程有限公司
中文关键字:1-辛烯;齐聚;配体
英文关键字:1-octene;oligomerization; catalysts ligand
中文摘要: 综述了铬系催化剂催化合成1-辛烯的进展。目前,主要是集中在PNP配体的研究,也取得了较好的试验结果,本文还介绍了乙烯四聚合成1-辛烯的反应机理,以对乙烯四聚合成1-辛烯催化剂有所促进,尽快实现该技术的产业化。
英文摘要: This review summarizes the recent advances in the studies of ethylene oligomerization by chromium-based homogeneous catalysts . High selectivity and activity catalyst system to produce 1-octene is the main research direction in future. Recently, the central type of PNP(tetramerization) ligand will be keeping on studied. Mechanistic studies of ethylene tetramerization reactions were also illuminated, which have significant meaning in this field.